Flux Fusion Energy Costs: Electricity versus Gas

December 23rd, 2008

When comparing the benefits of electric powered fusion units versus gas fired units, one factor that is often overlooked is the running costs. Obviously the costs go beyond just the raw price of the gas and electricity, but here we will just focus on the cost of electricity consumption of the KATANAX K2 Electric Fluxer versus that of a typical 3 or 4 unit gas burner.

The K2 electric unit:
The instrument takes about 15 minutes to heat up to a hold temperature of 1000oC. At a power of 2750W (i.e. the max power) we have a ramp-up energy of 2750 W x 15 min / (60 min / hr) = 688 W/hr = 0.688 kWh (maintaining the holding temperature of 1000oC uses 1.38 kWh).

The typical “oxide” fusion method lasts 20 minutes from start to finish and uses 2065W of energy.
2065W x 20 min / (60 min) = 688 W/hr = 0.688 kW/hr (same as heat-up)

There are three different ways one can use the instrument and each has a different energy usage:

  1.  Start from cold state then run only one fusion:
  2. Energy = (ramp-up) + (fusion cycle) = 0.688 + 0.688 = 1.38kWh per fusion

  3. Continuous fusions:
  4. 24/7:Daily = (average power) x (hours per day) = 2065W x 24 = 50 kW per day

  5. Instrument always on, but fuses only a fraction “f” of the time:
  6. Power = (f %) x (average fusion power) + (1-f %) x (standby power)
    Daily eg: fusion 30% (f=30%) avg power = 1577 W; Daily=1577W x 24h=38kWh

The typical gas unit:
For this discussion we will focus only on consumption/cost of gas.

From internet information it appears the maximum gas consumption is approximately 19L of propane gas per minute.  The expansion ratio of LPG is approx 250:1, therefore 1 liter of LPG yields 250L of propane gas.
At a consumption rate of 19 L/min (maximum), 1 liquid liter of LPG will last 250/19 = 13 minutes, meaning the unit uses about 5 liters of liquid LPG per hour.

For comparison to the three cases above:

  1. Not applicable for gas units
  2. Continuous fusions, 24/7
  3. (Liters per hour) x (hours in day) = 5 x 24 = 120L/day

  4. Fusions only a fraction “f” of a day
  5. (Liters per hour) x (hours in day) x (f /100)
    Example: fusions 30% of the day (f=30%) = 5 x 24 x 0.3 = 36L/day

The calculations for the gas unit are not as concise as for the electric unit, as the average consumption of gas in an approximation.

The Relative Costs:

Obviously the costs of LPG and electricity vary all round the world and are dependent on the time of year, economic factors, etc.  The costs below, for the discussion here, were from recent UK rates.

Case 2, Continuous fusions:

  • Electrical unit uses 50kW per day.  In the UK a domestic kW costs approx 12p, therefore the total cost would be 50 x £0.12 = £6.00
  • LPG unit uses 120L per day.  In the UK LPG costs 55p/L so the total cost would be 120 x £0.55 = £66.00

Case 3,  30% of time spent doing fusions:

  • Electrical unit uses 38kW/h per day.  1 kW costs approx 12p in the UK, so the total cost would be 38 x £0.12 = £4.56.
  • LPG unit uses 36L/day.  LPG costs 55p/L in the UK, so the total cost would be 36 x £0.55 = £19.80

I would stress again that these calculations use a number of assumptions and therefore are not completely accurate.  However it appears that the energy costs are approximately 4 to 10 times higher for a gas burner unit compared to the electric the K2 unit.

Calories in various wines and other alcoholic drinks

November 21st, 2008

The table below lists the approximate calories in an average (115ml or 4 oz) glass of wine.  Wine can contain up to 15% alcohol by volume and alcohol contains 7 calories per gram.  The more alcohol a wine contains the more calories, obviously.  For comparison, on average, the same 115ml of beer has 60 calories, light beer 35 calories and non-alcoholic beer 20 calories, but no one I know stops at 115ml.  Note that one gram of fat contains 9 calories and soda….forget it.  I think I initially switched to wine to lose weight, dry red of course.  Find more information on beer at: http://www.brewery.org/library/.

Alcohol in Wine

Wine # Calories
Alcohol-free Wine 37 calories
Champagne 100 calories
Dry Red 83 calories
Dry White 77 calories
Rose 82 calories
Sparkling White 92 calories
Sweet White 103 calories

Alcohol in Fortified Wines

Fortified Wine # Calories
Bianco Vermouth 167 calories
Ginger Wine 190 calories
Martini Bianco 150 calories
Martini, Extra Dry 150 calories
Martini Rose 180 calories
Martini Rosso 192 calories
Port 170 calories
Sherry 140 calories

For comparison

Drink # Calories
Beer, 12oz 175 calories
Beer, light, 12oz 105 calories
Beer, non-alc, 12oz 60 calories
Cosmopolitan, 4oz 200 calories
Gin & Tonic, 7oz 200 calories
Long Is Ice Tea, 8oz 780 calories
Margarita, 8 oz 280 calories
Martini, 3oz 200 calories
Mojito, 8oz 215 calories
Rum & Coke, 8oz 185 calories
Vodka & Tonic, 8oz 200 calories

Downtown London… interesting places you don’t find in a travel book

November 10th, 2008

Wine Bars

Gordon’s wine bar… A MUST, basement down Villiers St. next to Charring Cross Station. Very old, buy a bottle and drink it in the arched candle lit rooms or outside in the courtyard.

Cork and Bottle Wine Bar… almost as neat as Gordon’s, wider wine and food selections. In the basement with interesting little carved-out rooms. 44-46 Cranbourn St. just off Leicester’s Square near the tube stop.

Bedford & Strand Wine Bar… 1A Bedford Street just off the Strand near Charing Cross, nice selections and atmosphere. Not as crowded.

Café Des Amis…upscale wine bar near royal Opera House and Covent Garden, Bow St to Horal to 11 Hanover Place (alley) 020 7379 3444

The Savoy Hotel on The Strand is a famous old hotel and really neat to just go, have a glass of wine and take in the atmosphere

Covent Garden…good shops, stalls, good street performers, nice wine bar/restaurant in bottom of stall area, great restaurants and pubs.

Mexican

La Perla Mexican Bar… 28 Maiden Lane, WC2 near Covent Garden. Mexican food and drinks.

Also Café Pacifico… 5 Langley Street, W2 Locations in Paris also.

Wahaca Mexican Market Eating… Neuvo Mexican, Maiden Lane Covent Garden

Jazz & Blues clubs

Ronnie Scotts…premier jazz club of London. Frith street in SOHO, go to listen not great food, some great acts some mediocre

“Ain’t ‘nuthin But” blues club on Kingly St., near Oxford Circus and Carnaby Street, young crowd, somewhat seedy, may not like it, local blues bands, open mike Sunday starts 4pm.

“Spice of life” blues, Cambridge Circus, Tuesdays

“Adelaide Road Pub”, blues, Clark Farm tube station, Tuesdays

“Heathcote Public House” blues jam Leytonestone tube station, E11 bus, Wednesday

“Globe Public House”, blues, Morning Lane E8, Monday

“Town Hall”, blues, Mare St., Bethnal Green tube station, Bu 254

Around London

Dirty Dick’s Pub, near the Liverpool Street Station, financial district (One of???) The oldest Pubs in London, est 1745.

Great Queen Street, Queen Street, Traditional English food

Carnaby Street, Oxford Circus, good shopping, trendy shops, Liberty dept store, great Soccer/Rugby store, interesting pubs

Camden Town, lots of “crazy” young people; too much “flea market” to imagine, ethnic food, old London Locks/Boats, very crowded on weekends , really neat but had a real bad fire and I am not sure how much is left.

Old Spitafield Market, the Brickline Market and the High Sunday Market. New and old things and lots of ethnic food from everywhere in a very crowded and diverse neighborhood. Similar to Camden Town, near the Liverpool tube stop

SOHO, “Bohemian” area, very, very interesting people watching, china town….be careful

Tourist musts

Greenwich observatory museum, take the Thames river boat shuttle, great views, stand on the prime meridian, read about the longitudinal clocks before you go, I love mechanical antiques.

Tower military museum, really great dark ages armament neat tour by the beefeaters, royal jewels.

Westminster Chapel, very historic. War rooms.

Cork Taint in wine

October 30th, 2008

Cork Taint in Wine  If you ever opened a bottle of wine and immediately were hit with a pungent odor (not vinegar) you know what I want to discuss here: “

Cork
Taint” or wine that is “Corked”.  The term “Corked” is a broad term that people use to describe many undesirable smells and tastes in wine arising from spoilage to storage conditions to wooden barrels to just bad grapes.  
  However the chief cause is believed to result from the compound, 2,4,6-trichloroanisole, TCA.  The human threshold for TCA is in the single-digit parts per trillion, varying by several orders of magnitude depending on an individual’s sensitivity.  The smell has been described as mold, wet dog, phenol, chlorine, and others.  While harmless, TCA can make a wine undrinkable, except perhaps by me.   SPEX CertiPrep has been working on detection limits and the development of reference materials for 2,4,6-Trichloroanisole.  As you may know most cork comes from cork trees grown in

Portugal
.  The production is mostly from mom and pop business where the bark is striped, spread out to dry and treated with a chlorine containing chemical.  The chlorine chemicals are believed to react with phenolic compounds in the cork resulting in cork taint, i.e. 2,4,6-Trichlorophenol.  Some people believe these phenolic compounds come from fungi in the cork or in the air.
  A number of vintners are beginning to use twist off caps for white wines, as un-classical a way of sealing wine as it is, because it provides a great seal.  For reds, synthetic corks are not as good as they should be, but they are improving and will eventually compete with natural cork, especially if cork taint continues to be a problem.  www.spexcsp.com

Caffine and calories in beverages and energy drinks

October 30th, 2008

Caffeine in Beverages

Beverage / Drink Calories (kcal) Carbs (g) Sodium (mg) Volume (oz) Caffeine/Vol (mg) Caffeine/12oz (mg)
Water 0 0 0 na 0 0
Gatorade 50 14 110 8 0 0
Gatorade Endurance 50 14 200 8 0 0
Powerade 64 17 53 12 0 0
Coke Classic 140 39 50 12 35 35
Sunkist 190 52 45 12 41 41
Pepsi 100 27   12 38 38
Dr. Pepper 150 39   12 41 41
Mountain Dew 110 31   8 37 56
Brewed Coffee (avg) 0 0 0 8 150 225
Decaf Coffee 0 0 0 8 6 9

Caffeine in Energy Drinks

Beverage / Drink Calories (kcal) Carbs (g) Sodium (mg) Volume (oz) Caffeine/Vol (mg) Caffeine/12oz (mg)
Amp 114 30   8.4 75 107
SoBe Adrenaline 120 31   8.3 79 114
Red Bull 106 27 193 8 80 116
Full Throttle 220 58   16 144 108
Monster 200 52   16 160 120
Hi Ball Energy 4     8 60 90
Hype Energy Drink 114 27   8 77 116
Fixx       20 500 300
Wired X505       24 505 253

WInes of Obie’s Out of Bounds 2006 – 2008

May 9th, 2008

Obies Wines - 2006-2008

# Wine Type Blend Origin Barrel # # Gallons Crush Date Barrel Date Comments
18 Cabernet-Malbec 70% - 30% Chile 446 60 10-May-08    
17 Zinfindel, Old Vine   California NA 60 21-Sep-07 27-Jun-08  
16 Chateanueuf-du-Pape   California 444 60 29-Sep-07 28-Jun-08 Grenache, Cab, Mer, Cab Franc, Mal
15 Sanatra Blend 33% - 33% - 33% California 443 60 27-Sep-07 19-Jun-08 Cabernet, Merlot, Cab Franc
14 Merlot   Chile 466 60 11-May-06 18-May-07  
13 Zinfindel   California 443 60 21-Sep-06 12-Jul-07  
12 Barolo 50% - 40% - 10% California 444 60 28-Sep-06 08-Jun-07 Nebbiolo, Barbera, Petite Sirah

Ageless (mostly conservative) wit and observations

January 29th, 2008

‘If you don’t read the newspaper you are uninformed, if you do read the newspaper you are misinformed.’
-Mark Twain


Suppose you were an idiot. And suppose you were a member of Congress…. But then I repeat myself.
-Mark Twain


I contend that for a nation to try to tax itself into prosperity is like a man standing in a bucket and trying to lift himself up by the handle.
-Winston Churchill


A government which robs Peter to pay Paul can always depend on the support of Paul.
-George Bernard Shaw


A liberal is someone who feels a great debt to his fellow man, which debt he proposes to pay off with your money.
-G Gordon Liddy


Democracy must be something more than two wolves and a sheep voting on what to have for dinner.
-James Bovard, Civil Libertarian (1994)


Foreign aid might be defined as a transfer of money from poor people in rich countries to rich people in poor countries.
-Douglas Casey, Classmate of Bill Clinton at

Georgetown

University

Giving money and power to government is like giving whiskey and car keys to teenage boys.
-P.J. O’Rourke,

Civil Libertarian Government is the great fiction, through which everybody endeavors to live at the expense of everybody else. -Frederic Bastiat, French Economist (1801-1850)  Government’s view of the economy could be summed up in a few short phrases: If it moves, tax it. If it keeps moving, regulate it. And if it stops moving, subsidize it.
-Ronald Reagan (1986)


I don’t make jokes. I just watch the government and report the facts.
-Will Rogers


If you think health care is expensive now, wait until you see what it costs when it’s free!
-P.J. O’Rourke


In general, the art of government consists of taking as much money as possible from one party of the citizens to give to the other.
-Voltaire (1764)


Just because you do not take an interest in politics doesn’t mean politics won’t take an interest in you!
-Pericles (430 B.C.) 
 

No man’s life, liberty, or property is safe while the legislature is in session.
-Mark Twain (1866 )

Talk is cheap…except when Congress does it.
-Unknown


The government is like a baby’s alimentary canal, with a happy appetite at one end and no responsibility at the other.
-Ronald Reagan

The inherent vice of capitalism is the unequal sharing of the blessings. The inherent blessing of socialism is the equal sharing of misery.
-Winston Churchill


The only difference between a tax man and a taxidermist is that the taxidermist leaves the skin.
-Mark Twain


The ultimate result of shielding men from the effects of folly is to fill the world with fools.
-Herbert Spencer, English Philosopher (1820-1903)


There is no distinctly Native American criminal class…save Congress.
-Mark Twain

What this country needs are more unemployed politicians.
-Edward Langley, Artist (1928 – 1995)


A government big enough to give you everything you want, is strong enough to take everything you have.
-Thomas Jefferson

ISOTOPE DILUTION FOR THE ANALYSIS OF METALS IN PLASTICS

October 8th, 2007

ISOTOPE DILUTION FOR THE ANALYSIS OF METALS IN PLASTICS  Ralph Obenauf, Vanaja Sivakumar, Laszlo Ernyei, Bill Driscoll, SPEX CertiPrep, Inc. 203 Norcross Avenue, Metuchen, NJ 08840, robenauf@spexcsp.com 

www.spexcsp.com

     The European Directive, Restriction of Hazardous Substances (RoHS) & Waste Electrical and Electronic(WEEE) restricts the use of hazardous substances such as  lead, cadmium, chromium(VI), mercury and brominated polybihphenyl ethers  in electronic and other equipment.  The RoHS & WEEE directives set only a minimum standard.  Different countries have set their own regulations and requirements.                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                             Various analytical methods are employed to determine the concentration of restricted substances.  Most methods require some sample preparation such as digestion or extraction.  Many of the methods currently used are not appropriate for all products tested, and results differ from method to method.  It is vital to develop standard methods that produce reliable results that can be implemented by all laboratories.  We have developed a method for accurate analysis of the above metals in plastic.       Methods based on direct analysis of solid samples by XRF and Laser Ablation ICP-MS are limited due to the lack of calibration standards for various complex plastic matrices.  Methods based on destructive sample preparation usually employ heating the polymers with mineral acids or dissolution in organic solvents [1].  However, heating with acids may lead to the loss of analytes due to volatilization and many polymers are sparingly soluble in organic solvents.  Here we employed two techniques for sample preparation, namely, conventional ashing and microwave digestion.       Isotope dilution Mass Spectrometry (IDMS) is based on the addition of a known quantity of an enriched isotope to a sample. Equilibration of the spike isotope with the natural element in the sample alters the isotope ratio that is measured. Knowing the isotopic abundance of both spike and sample, the amount of spike added to the known amount of sample, the measured concentration of the spike added and the altered isotope ratio, then the concentration of the element in the sample can be calculated [2].  Since elements of interest such as Cd, Cr and Pb in the RoHS directive have two or more naturally occurring isotopes, the isotope dilution technique presents an interesting solution for the determination of these elements.       Ashed polyethylene polymer dissolved in nitric acid was analyzed for cadmium, chromium and lead. The polymer was spiked with a known amount of cadmium enriched with Cd-106, chromium enriched with Cr-50 and lead enriched with Pb-206; then ashed.  Both spiked and un-spiked polyvinyl chloride and polyethylene polymers were also digested in a combination of nitric, hydrochloric, hydrofluoric acid along with hydrogen peroxide.     The IDMS technique results in higher accuracies in the determination of lead, chromium and cadmium than conventional calibration methodology.   Partial loss of analyte due to sample preparation or the complexity of the matrix did not affect the accuracy of determination.   References: 1. Digestion of Plastic Materials for the Determination of Toxic Metals with a Microwave Oven for Household Use: Hiroki Sakurai et al, Analytical Sciences, February 2006, Vol.2.2. USEPA Method 6800: Elemental and Speciated Isotope Dilution Mass Spectrometry. 

Favorite Lyrics and Quotes

September 25th, 2007

Quotes 

“Pain is fear leaving the body.” 

“Whatever Doesn’t Kill You Makes You Stronger.”  Friedrich Neitzche 

“To whom much is given, much is required.”  John F. Kennedy 

“God comes to the hungry in the form of food.”   Mahatma Gandhi 

“They cannot take away our self-respect if we do not give it to them. “   Mahatma Gandhi 

“The journey is the reward.”   Tao Saying 

“If you don’t fail now and again, it’s a sign you’re playing it safe. If you don’t fail now and again, it’s a sign you aren’t aiming high enough.”    Woody Allen 

God grant me the serenity to accept the things I cannot change, courage to change the things I can, and wisdom to know the difference. 

“There is neither happiness nor misery in the world; there is only thecomparison of one state with another, nothing more. He who has felt thedeepest grief is best able to experience supreme happiness. We must havefelt what it is to die, Morrel, that we may appreciate the enjoyments ofliving.” – Alexandre Dumas – “The Count of Monte Cristo” 

“We boil at different degrees.”   Ralph Waldo Emerson. 

Blowing out another’s candle will not make yours shine brighter. 

I refuse to engage in an intellectual battle with an unarmed man. 

Some days you’re the dog, and some days you’re the hydrant. 

Eat shit! 1,000,000,000,000 flies can’t be wrong. 

“Guests and fish start to stink after two days.”   Spanish Proverb. 

The hardest thing to learn in life is which bridge to cross and which to burn. 

“Patience has its limits. Take it too far, and it is cowardice.”  George Jackson. 

The gene pool could use a little chlorine. 

If you step in a puddle, don’t blame the puddle. 

A fine is a tax for doing wrong…..A tax is a fine for doing well. 

A government bureau is the nearest thing to eternal life we’ll ever see on this Earth” Ronald Regan   “A time for choosing” 

Lyrics 

“Bury the hatchet, but leave the handle stickin’ out.” Garth Brooks, “We Bury The Hatchet” 

“Sometimes you’re the windshield, sometimes you’re the bug.”  Dire Straits, “The Bug”                         

“Savor the throne, but don’t mind the stool.” Steve Winwood, “Take It As It Comes” 

“Every pleasure’s got an edge of pain, pay for your ticket and don’t complain.” Bob Dylan, “Silvio”                       

“The ones that you’re calling wild are going to be the leaders in a little while.” Johnny Cash, “What Is Truth”                         

“When the grass is cut, the snakes will show.” Jay-Z, “Blueprint 2″                         

“The pain of war cannot exceed the woe of aftermath.” Led Zeppelin, “The Battle Of Evermore”  

“Free your mind and your ass will follow.” Funkadelic, “Good Thoughts, Bad Thoughts”                         

“Life is what happens to you while you’re busy making other plans.” John Lennon, “Beautiful Boy (Darling Boy)”  

“Grace makes beauty out of ugly things.” U2, “GRACE” 

“It’s hard to remember we’re alive for the last time.”  Modest Mouse, “Lives” 

“An honest man’s pillow is his peace of mind.” John Mellencamp, “Minutes To Memories”                         

“If you follow every dream, you might get lost.” Neil Young, “The Painter”                         

“The best you can is good enough.” Radiohead, “Optimistic”                         

“No, it’s not love, but it’s not bad.” Merle Haggard, “It’s Not Love”                         

“If you want to hear God laugh, tell him your plan.”  Help somebody if you can                       

“I make money but I still feel broke.”  The Clarks – Fast moving Cars.                          

“What kinda gone?”  Chris Cragle

Matrix Effects in ICP-OES Analysis

August 17th, 2007

Matrix effects in ICP-AES analysis

Ralph Obenauf and Vanaja Sivakumar

SPEX CertiPrep, Metuchen, NJ

The sample “matrix” is the bulk composition of the sample such as water, organic compounds, acids, dissolved solids and salts, etc. Matrix effects can influence the ability of an analytical method, to qualitatively identify and quantitatively measure target compounds in environmental and other samples, by indirectly affecting the intensity and resolution of observed signals. To obtain defensible results the analyst must account for all matrix effects. In ICP-OES analysis the ionic-to-atomic line intensity ratio can be used as an indicator for determining plasma related matrix effects. Elements such as sodium and calcium, which are ubiquitous in nature, have low ionization potentials and as a consequence are some of the most easily ionized elements. In this study the influence of sodium as well as the acid concentration on the ionic-to-atomic intensity ratio of chromium, cadmium and lead has been investigated.

Effect of Sodium concentration:

We observed a considerable change in the recovery of cadmium and chromium, which exhibits a profound influence on these analytes by varying the concentration of Sodium. The relative intensity of chromium and cadmium atom lines were much higher than the respective ionic lines for these analytes. The effect is significant even at 50 ppm sodium. The lead concentration is affected, relatively, less by the change in the sodium concentration.

Effect of acid concentration:

The matrix effect due to changes in the acid concentration was very significant for cadmium and lead in nitric acid, While the chromium atomic line was unaffected, a decrease was observed in the in intensity for the chromium ionic line. The higher the acid concentration, the lower the intensity for lead and cadmium, and therefore resulting in poorer detection limits. We observed much smaller changes in analyte recoveries for increases in hydrochloric acid concentrations when compared with comparable nitric acid concentration changes.Matrix effects have a profound effect on the accuracy of trace elemental analysis by ICP. Excess acid from acid digestion can be a source of error in the analysis. Because of the different behavior of the atomic and ionic lines, at least two internal standards are needed to compensate for matrix effects. It is absolutely essential to match the sample matrix to the standard to assure accurate and defensible data. www.spexcsp.com